RUTHENIUM ACETYLACETONATE

Synonyms. Ruthenium acetylacetonate; Tris(pentane-2,4-dionato-O,O')ruthenium; Ruthenium(III) acetylacetonate; Tris(2,4-pentanedionato)ruthenium; Tris(acetylacetonato)ruthenium; Tris-acetylacetone-ruthenium (III); Ru(acac)3; Ruthenium 1,1,1-trifluoropentane-2,4-dione;

RUTHENIUM ACETYLACETONATE

Click for original image

 

PRODUCT IDENTIFICATION

CAS RN

14284-93-6

EINECS RN

238-193-0

FORMULA

Ru(C5H7O2)3

MOLE WEIGHT

398.39

H.S CODE

2843.90.0000

SMILES

[Ru+3].O=C(C)[CH-]C(=O)C.O=C([CH-]C(=O)C)C.O=C([CH-]C(=O) C)C

CLASSIFICATION

Ruthenium compound, Acetylacetonate complex

EXTRA NOTES

Application;Catalyzes the hydrogenation of dimethyl oxalate to ethylene glycol under mild conditions [sigmaaldrich]

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

dark violet powder

MELTING POINT

260 C

BOILING POINT

 

DENSITY

1.54 g/cm3

SOLUBILITY IN WATER

Insoluble

SOLVENT SOLUBILITY

Soluble in most organic solvents

VAPOR DENSITY

 

log P(octanol-water)

 

VAPOR PRESSURE

 

AUTOIGNITION TEMP

 
pK

 

REFRACTIVE INDEX

 

FLASH POINT

 

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions.

INCOMPATIBLE MATERIALS

Strong oxidizing agents.

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 2, Flammability: 1, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Ruthenium acetylacetonate

Wikipedia Linking - Ruthenium acetylacetonate

Google Scholar Search - Ruthenium acetylacetonate

U.S. National Library of Medicine - Ruthenium acetylacetonate

PubChem Compound Summary - Ruthenium acetylacetonate

NCBI (http://www.ncbi.nlm.nih.gov/) -  Ruthenium acetylacetonate

Material Safety Data Sheet - Ruthenium acetylacetonate

EPA - Substance Registry Services - Ruthenium acetylacetonate

 

SALES SPECIFICATION

APPEARANCE

dark violet powder

PURITY

99.5% min

Ru CONTENT

25% min

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

 

HAZARD CLASS

 

PACKING GROUP  

 

SAFETY INFORMATION

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Skin irritation. Eye irritation. Specific target organ toxicity - single exposure. Hazard statements: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

SIGNAL WORD Warning

PICTOGRAMS

PICTOGRAM_GHS07_exclamation.jpg

HAZARD STATEMENTS

H315-H319-H335

P STATEMENTS

P261-P264-P271-P280-P302 + P352-P304 + P340P305 + P351 + P338-P312-P321-P332 + P313-P337 + P313

EC DIRECTIVES

 

HAZARD CODES

CODE_Xn_Xi_harmful_Irritant.gif

RISK PHRASES

36/37/38

SAFETY PHRASES

26-36

 

PACKING

Preserved in light-resistant and well-closed bottles